

| Subject: | Re: Electronic Rust Protection? |
| From: | David Beierl |
| Date: | Wed, 8 Aug 2001 10:35:07 -0400 |
It ain't *quite* that simple, Terry -- At 09:41 AM 8/8/2001, Terry Kay wrote: >But an electrical imbalance that causes rust? Absolutely. Rusting is an electrochemical reaction (or rather set of reactions, see <http://antoine.fsu.umd.edu/chem/senese/101/redox/faq/how-iron-rusts.shtml> for some pathways. But the fundamental process underlying rust formation is that the iron loses electrons. In fact the current definitions of oxidation boil down to "losing electrons." One method of corrosion control involves supplying excess electrons which use up the reactive elements before they can strip electrons from the iron. This can be done by using electrodes such as magnesium or zinc which provide electrons by sacrificing themselves, or by actively impressing an electric current on the system. Both methods are extensively used on ships, pipelines, buried tanks etc. HOWEVER...the snag is this whole system works *within the fluid where the corrosion is taking place." If you have a ship in salt water, or a pipeline buried in conductive earth, this is quite practical. But on a land-based system where the corrosion is taking place in tiny isolated places, it becomes a practical impossibility to get the current to where you need it. You have to have a continuous conducting medium to complete the circuit. So on the face of it, automobiles are not a good candidate for impressed-current cathodic protection, unless you're burying them or dropping them in the sea. The wiggle room, if any (and I haven't yet seen absolute proof one way or the other, though the anticorrosion professionals tend to fall down laughing when the subject is mentioned) is whether salt splash etc. can provide a sufficiently continuous electrolyte medium for this method to have any effect. >I don't think so. > >Then I want to know where my "cathode", and "anode" portion of my >vehicle is located, so I can tend to them immediately. Every tiny speck of rust has one (or many) cathodes and anodes. Fix the rust and you'll have tended your a's and c's... david David Beierl - Providence, RI http://pws.prserv.net/synergy/Vanagon/ '84 Westy "Dutiful Passage" '85 GL "Poor Relation"
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