

| Subject: | Re: Comments on plastic repair/Epoxies in General(a little long) |
| From: | Jim Felder |
| Date: | Wed, 7 Feb 2007 12:46:02 -0600 |
Thanks, That's worth printing out. BTW the adhesive I used was $4.99, pretty pricey but way below the cost of an OEM cup holder. Dylan wrote this morning about using a plastic welder, but I don't know how it would be used on tiny, barely-accessible parts like I fixed yesterday. I did take apart my 90 carat's vacuum pump in the cruise control system and found the plastic un-gluable upon reassembly. So I went around the seam I cut with a dremel tool with a soldering iron and fused it back together. While it made a good seal, I don't think that "welded" repair would bear a lot of weight if required to. Jim On Feb 7, 2007, at 12:24 PM, Max Wellhouse wrote: > Jim and Listees: I have posted anecdotally on several occasions > about this strain of adhesives. Although I'm not a chemical > engineer, part of the confusion with this stuff is that people call > anything with a two-part mixing step "epoxy", whether it comes in a > black or clear syringe, two metal cans, or a block of putty you > mush together to get it to kick.. The Plastic Welder series of > adhesives are based on a compound call methyl-methacrolate and yes > it does stink. If you are unsure of whether you are buying a > plastic welding glue or epoxy, read the fine print on the back of > the placard in which the syringe is stored. If it mentions Amines > etc, it's more of an epoxy. If it mentions, methacrolate or methyl- > methacrolate, well..... > > The Plastic Welder Jim used so successfully is marketed by several > different companies, but the most accessible is the Devcon Plastic > Welder sold(and sometimes mis-stocked) at Wal mart. to the casual > observer/shopper at WM, these syringes pretty much look all the > same. More on that later. The 50cc syringes are a whopping $2.27 > each!! Napa/AutoZone/Checker/etal as well as Walgreens etc. sell > this stuff under various brand names, but charge considerably > more. This product claims to have a breaking strength of 3000#, > 90% of which occurs after 30 minutes of curing. Full cure in 24 > hours. Clamping/pressure/weighting the bond can improve the > bonding strength for sure. You have to work quickly with it, > especially in hot weather, so mixing only what you will use in 5 > minutes is the key. It doesn't hurt to sand slick surfaces and > clean foreign material from the bonding surfaces as well. My guess > is that the methacrolate actually melts part of the bonding > surfaces and that's where the "weld" part of the product > description comes into play. The super duper expensive version of > this stuff is made by a company in New England and is called > Plexus. For those of you needing a color match on your repairs, > the Plexus is a gray color, but not worth the extra cost for my > needs. I uasually travel with a syringe of the Devcon stuff even > though it's so readily available. My 50cal. metal ammo box holds > all my other epoxy and kevlar repair stuff. > > At some point I intend to experiment with some resin colorants I > have for my Gougeon Brothers epoxy by mixing them into the Plastic > welder to see if coloring the adhesive weakens it's bond. I pretty > much know the answer to that before I do it, but my supplier says > 1-2% by volume is all you should use with polyester/vinylester, and > epoxy resin systems, and I have a feeling even mixing all 50cc of > the Plastic Welder even for a small repair, adding just .5 cc of > resin colorant would be hard to measure and likely wouldn't change > the color substantially anyway. Black may be an exception. Really > small amounts I would think to be impossible. > > I have successfully bonded 1.5"x4" polycarbonate plates (with 1.5" > metal D-rings in the middle of them) to the vinyl interior skins of > ABS and kevlar/fiberglass canoes. In the years in which I > outfitted whitewater boats for a second income, I never had one of > these plates pull up and they took some serious stress(anchoring > thigh straps) and taking major trauma when the boat struck rocks > beneath the water's surface(hull flexing, not actually having the > rings on the outside of the boat!!).. > > As for the other adhesives called epoxies, there are some caveats > as well. The "5 minute epoxies" set up quickly, but read the fine > print on most of their packages, most of the quick setting epoxies > are not waterproof. Even my beloved Gougeon Brothers epoxy doesn't > tolerate high temperatures. I tried to repair a steam gun for a > clothing shop once and the steam pretty much melted the epoxy > down. It was a plastic repair, but prior to me discovering the > Plastic Welder stuff. I would've loved to try the PW on the high > temp application. As a general rule, the epoxies and fiberglass > resins you buy off the shelf have to compromise bonding strength > for shelf life. Polyester and vinylester resins require a really > nasty catalyst called Methyl Ethyl Ketone Peroxide(MEKP). Not only > does the resin have an offensive odor, but the MEKP finds its way > into your eyes, you can go blind. The epoxies cost more, but > usually bond better and most don't have the odor issues. Without > adequate ventilation, a respirator should be worn regardless of > odor or not. The Gougeon engineers test their resin for shelf life > and have samples from 20 years ago that still have 90% bond > strength, they just get more viscous with time and wetting out > densely woven cloths becomes difficult getting all the air bubbles > removed. The hardeners tend to absorb moisture from the air and > with time and change color, but their shelf life would still be > adequate. I have hardener that 5 years old and severely > discolored, but still kicks when its supposed to. If I have a > repair that needs to be clear, I'll use fresh hardener. > > None of these adhesives will bond polyethylene, as it needs to be > "welded" with a "hot air" plastic welder and I never got the hang > of that. Old Town Canoes sells both a "repair" kit and a "grunch > pad" kit for its Discovery line of cross-linked polyethylene > canoes, but that urethane-based resin system is very expensive, has > a very short shelf life, and kicks very quickly after mixing. You > also have to "polarize" the plastic surface to be bonded with the > brief passing of the inner blue cone flame of a propane torch to > get the urethane to bond to the poly. I hated fixing those > boats!! Cheap to buy, but expensive to repair > > The last item I'd like to mention is that the polyester and > vinylester resins are really difficult to tell when they're "over > the hill". By that I mean their shelf life has come and gone. I > once used old polyester to try to fix something and even though I > used 4% MEKP, 6 hours later the repair is still gooey at 60 degrees > F. The point is, you can't look at it and tell whether it's still > good or not and cleaning up all that gooey crap and starting over > again just isn't worth it. Hopefully you novice"bonders" out there > know a little more about all this stuff now. > > . > > So much for that epistle. > > DM&FS > > > > 10:08 AM 2/7/2007, Jim Felder wrote: > >> For those of you who have tried to used epoxy to repair broken >> plastic items, you've probably been underwhelmed at the results, >> especially when gluing together chipped and broken pieces (bonding >> one flat surface to another usually works fine, it's the pieces that >> crack through and need repair that seldom hold). >> >> Yesterday, a four-legged passenger jumped into a front seat and >> damaged an open cup holder. As much as the OEM holders cost, I >> thought I'd pick up some epoxy and give it a try, but I didn't expect >> much as I had not had good success in the past when the pivots broke >> off of the lower part of the holder. >> >> One of my FLAPS had something called NAPA Plastic Welding Systems. >> Don't use it in a room you're going to be breathing in! It REAALY >> stinks. It is a 2-part epoxy, of course, and it dries a milky white, >> so I used as little as possible on the black cup holder. >> >> In a couple of hours came the moment of truth... would the repair >> withstand being forced over the protruding hinge pins? It did. I put >> a little silicon lube in the joints and on the metal spring plates, >> and the original "snap" came back the holder, all ready to go back in >> today. >> >> For stuff like repairing heater vent covers and broken off heater >> valve cover pins, where strength is required but not much bonding >> surface is available, it looks to be the stuff. >> >> Jim >> >> >> >> -- >> No virus found in this incoming message. >> Checked by AVG Free Edition. >> Version: 7.1.411 / Virus Database: 268.17.28/672 - Release Date: >> 2/6/2007 > > > -- > No virus found in this outgoing message. > Checked by AVG Free Edition. > Version: 7.1.411 / Virus Database: 268.17.28/672 - Release Date: > 2/6/2007 > > >
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