

| Subject: | Re: Speaking of batteries... |
| From: | Alistair Bell |
| Date: | Wed, 19 Apr 1995 22:58:39 -0700 (PDT) |
Dug up the ol' chemical reaction that goes on in a battery. Take a deep breath: remember, the battery is made up of alternating lead and lead oxide plates, with sulfuric acid as an electrolyte. the electrolyte contains hydrogen ions (H+) and sulphate ions (SO4--). During discharge, H+ ions react with the lead(IV) oxide to give lead(II)oxide and water; PbO2 + 2H+ + 2e- -> PbO + H2O the reaction takes electrons from the plate, causing a positive charge. There is a further reaction to yield soft lead sulphate; PbO + SO4-- + 2H+ -> PbSO4 + H2O + 2e- electrons are released to the electrode, producing a negative charge. You can see how the production of H2O accounts for the lower specific gravity in a discharged battery. During charging the reactions are reversed; PbSO4 + 2e- -> Pb + SO4-- PbSO4 + 2H2O -> PbO2 + 4H+ + SO4-- + 2e- Now the specific gravity of the electrolyte (sulfuric acid) increases. I still can't see where EDTA would fit in. I don't see any divalent cations... Alistair
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